Identification of ONO⋯ONO interactions among inorganic coordination complex molecules in the crystal lattice of a chiral Mn(IV) compound

dc.contributor.author Pradeep, Chullikkattil P.
dc.contributor.author Zacharias, Panthapally S.
dc.contributor.author Das, Samar K.
dc.date.accessioned 2022-03-27T08:43:58Z
dc.date.available 2022-03-27T08:43:58Z
dc.date.issued 2008-01-01
dc.description.abstract The chiral Schiff base ligand H2L on reaction with Mn(CH3COO)2 · 4H2O in methanol gave a yellow precipitate, which on recrystallization from dimethylformamide (DMF) solvent solvent gave dark-brown needle shaped crystals of a chiral Mn(IV) compound [MnL2] · DMF (1). Crystal structure analysis of compound 1 revealed an interesting O⋯O non-covalent interaction between -NO2 groups present on adjacent [MnIVL2] complex units which leads to the formation of chainlike arrangement in the crystal lattice of the relevant complex. © 2007 Elsevier B.V. All rights reserved.
dc.identifier.citation Inorganic Chemistry Communications. v.11(1)
dc.identifier.issn 13877003
dc.identifier.uri 10.1016/j.inoche.2007.10.019
dc.identifier.uri https://www.sciencedirect.com/science/article/abs/pii/S1387700307003966
dc.identifier.uri https://dspace.uohyd.ac.in/handle/1/11635
dc.subject Chiral Mn(IV) complex
dc.subject Crystal structure
dc.subject Nitro-nitro interaction
dc.subject Supramolecular chemistry
dc.title Identification of ONO⋯ONO interactions among inorganic coordination complex molecules in the crystal lattice of a chiral Mn(IV) compound
dc.type Journal. Article
dspace.entity.type
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