Studies on Horner-Wadsworth-Emmons reaction in base sensitive ketones: Synthesis of (-)-mitsugashiwalactone and formal synthesis of (+)-iridomyrmecin, (-)-isoiridomyrmecin and (+)-teucriumlactone
Studies on Horner-Wadsworth-Emmons reaction in base sensitive ketones: Synthesis of (-)-mitsugashiwalactone and formal synthesis of (+)-iridomyrmecin, (-)-isoiridomyrmecin and (+)-teucriumlactone
| dc.contributor.author | Nangia, A. | |
| dc.contributor.author | Prasuna, G. | |
| dc.date.accessioned | 2022-03-27T09:35:33Z | |
| dc.date.available | 2022-03-27T09:35:33Z | |
| dc.date.issued | 1996-01-01 | |
| dc.description.abstract | The effect of different bases in promoting Horner-Wadsworth-Emmons (HWE) reaction on enolisable cyclopentanones is investigated. NaH is found to be suitable for the intermolecular reaction and DBU/LiCl is optimal for the intramolecular variation. The HWE approach is employed for the enantioselective synthesis of iridoid cyclopentapyranones of type-I (4, 16, 52) and type-II (5, 36). | |
| dc.identifier.citation | Tetrahedron. v.52(10) | |
| dc.identifier.issn | 00404020 | |
| dc.identifier.uri | 10.1016/0040-4020(96)00023-3 | |
| dc.identifier.uri | https://www.sciencedirect.com/science/article/abs/pii/0040402096000233 | |
| dc.identifier.uri | https://dspace.uohyd.ac.in/handle/1/13090 | |
| dc.title | Studies on Horner-Wadsworth-Emmons reaction in base sensitive ketones: Synthesis of (-)-mitsugashiwalactone and formal synthesis of (+)-iridomyrmecin, (-)-isoiridomyrmecin and (+)-teucriumlactone | |
| dc.type | Journal. Article | |
| dspace.entity.type |
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