Ruthenium-Catalyzed Hydroarylation and One-Pot Twofold Unsymmetrical C−H Functionalization of Arenes

dc.contributor.author	Ghosh, Koushik
dc.contributor.author	Rit, Raja K.
dc.contributor.author	Ramesh, E.
dc.contributor.author	Sahoo, Akhila K.
dc.date.accessioned	2022-03-27T09:59:39Z
dc.date.available	2022-03-27T09:59:39Z
dc.date.issued	2016-06-27
dc.description.abstract	A methyl phenyl sulfoximine (MPS) is used as a directing group in the ruthenium-catalyzed intramolecular hydroarylation of alkene-tethered benzoic acid derivatives to afford dihydrobenzofurans and indolines in good to excellent yields. A one-pot, unsymmetrical, twofold C−H functionalization involving intramolecular C−C and intermolecular C−C/C−N bond formations is successfully demonstrated by using a single set of catalytic reaction conditions, which is unprecedented thus far. A novel isoquinolone-bearing dihydrobenzofuran is constructed through an unsymmetrical twofold C−H functionalization.
dc.identifier.citation	Angewandte Chemie - International Edition. v.55(27)
dc.identifier.issn	14337851
dc.identifier.uri	10.1002/anie.201600649
dc.identifier.uri	https://onlinelibrary.wiley.com/doi/10.1002/anie.201600649
dc.identifier.uri	https://dspace.uohyd.ac.in/handle/1/13507
dc.subject	annulations
dc.subject	C−H activation
dc.subject	heterocycles
dc.subject	reaction mechanisms
dc.subject	ruthenium
dc.title	Ruthenium-Catalyzed Hydroarylation and One-Pot Twofold Unsymmetrical C−H Functionalization of Arenes
dc.type	Journal. Article
dspace.entity.type

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