A simple, direct synthesis of Na < inf > 2 < /inf > Fe(CO) < inf > 4 < /inf >
A simple, direct synthesis of Na < inf > 2 < /inf > Fe(CO) < inf > 4 < /inf >
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Date
1991-10-01
Authors
Devasagayaraj, Arockiasamy
Periasamy, Mariappan
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Abstract
Reduction of anhydrous FeCl3 in THF with sodium naphthalenide under a CO atmosphere at room temperature leads directly to Na2Fe(CO)4, which on reaction with alkyl bromides gives the corresponding aldehydes, ketones and carboxylic acids under appropriate conditions. © 1991 Chapmand & Hall.
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Transition Metal Chemistry. v.16(5)