Mimicking oxide surfaces: Different types of defects and ligand coordination at well defined positions of a molybdenum oxide based nanocluster
Mimicking oxide surfaces: Different types of defects and ligand coordination at well defined positions of a molybdenum oxide based nanocluster
| dc.contributor.author | Müller, Achim | |
| dc.contributor.author | Maiti, Rabindranath | |
| dc.contributor.author | Schmidtmann, Marc | |
| dc.contributor.author | Bögge, Hartmut | |
| dc.contributor.author | Das, Samar K. | |
| dc.contributor.author | Zhang, Wenjian | |
| dc.date.accessioned | 2022-03-27T08:44:58Z | |
| dc.date.available | 2022-03-27T08:44:58Z | |
| dc.date.issued | 2001-01-01 | |
| dc.description.abstract | The mixed valence cluster anion of the compound (NH4)32[MoVI110MoV28O416H6(H2O)58(CH3CO2)6]·xH2O 1 (x∼250), synthesized under one-pot conditions, contains well-defined different types of defects—missing groups compared to the complete parent {Mo154} type cluster with full D7d symmetry—and acetate ligand coordination; this proves that the giant-wheel type anion can be considered as an object with a variety of nanoscale structural features (“nanostructured landscape”) allowing reactions at a variety of well defined centers. © 2001 Royal Society of Chemistry. | |
| dc.identifier.citation | Chemical Communications. v.1(20) | |
| dc.identifier.issn | 13597345 | |
| dc.identifier.uri | 10.1039/b106092a | |
| dc.identifier.uri | http://xlink.rsc.org/?DOI=b106092a | |
| dc.identifier.uri | https://dspace.uohyd.ac.in/handle/1/11683 | |
| dc.title | Mimicking oxide surfaces: Different types of defects and ligand coordination at well defined positions of a molybdenum oxide based nanocluster | |
| dc.type | Journal. Article | |
| dspace.entity.type |
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