A new method for the regio and stereoselective hydrocarboxylation of alkynes using NaHFe(CO) < inf > 4 < /inf > /CH < inf > 2 < /inf > Cl < inf > 2 < /inf > system
A new method for the regio and stereoselective hydrocarboxylation of alkynes using NaHFe(CO) < inf > 4 < /inf > /CH < inf > 2 < /inf > Cl < inf > 2 < /inf > system
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Date
1997-03-03
Authors
Periasamy, Mariappan
Radhakrishnan, Ukkiramapandian
Rameshkumar, Chellappan
Brunet, Jean Jacques
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Abstract
The reagent generated in situ in THF using NaHFe(CO)4 and CH2Cl2 was used for the regio and stereoselective hydrocarboxylation of terminal and internal alkynes to obtain α,β-unsaturated carboxylic acid derivatives.
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Citation
Tetrahedron Letters. v.38(9)