The first one-dimensional heteropoly tungstovanadate coordination polymer: [(V < sup > V < /sup > O < inf > 4 < /inf > )W < inf > 8 < /inf > < sup > VI < /sup > M < inf > 4 < /inf > O < inf > 36 < /inf > (V < sup > IV < /sup > O) < inf > 2 < /inf > ] < sup > n- < /sup > (M = 0.71V < sup > IV < /sup > + 0.29W < sup > VI < /sup > , n = 4.68)
The first one-dimensional heteropoly tungstovanadate coordination polymer: [(V < sup > V < /sup > O < inf > 4 < /inf > )W < inf > 8 < /inf > < sup > VI < /sup > M < inf > 4 < /inf > O < inf > 36 < /inf > (V < sup > IV < /sup > O) < inf > 2 < /inf > ] < sup > n- < /sup > (M = 0.71V < sup > IV < /sup > + 0.29W < sup > VI < /sup > , n = 4.68)
| dc.contributor.author | Shivaiah, Vaddypally | |
| dc.contributor.author | Hajeebu, Swapna | |
| dc.contributor.author | Das, Samar K. | |
| dc.date.accessioned | 2022-03-27T08:44:49Z | |
| dc.date.available | 2022-03-27T08:44:49Z | |
| dc.date.issued | 2002-11-01 | |
| dc.description.abstract | An aqueous ammonium acetate buffer solution (pH 4) containing vanadate, tungstate and dithionite ions, on heating at 100 °C for 1 h yields one-dimensional polyoxometalate chain compound (NH4)4.68[(VVO4) W8VIM4O36(VIV O)2] · 12H2O (M = 0.71VIV + 0.29WVI) 1, which is characterized by single-crystal x-ray structure determination, redox titration, and IR spectroscopic studies. Crystallographic data for 1, H42.72N4.68O54V5.84 W9.16, tetragonal, space group I4̄, a = 15.8132(5), c = 11.1114(5) Å, Z = 2, V = 2778.5(2) Å3. © 2002 Elsevier Science B.V. All rights reserved. | |
| dc.identifier.citation | Inorganic Chemistry Communications. v.5(11) | |
| dc.identifier.issn | 13877003 | |
| dc.identifier.uri | 10.1016/S1387-7003(02)00621-4 | |
| dc.identifier.uri | https://www.sciencedirect.com/science/article/abs/pii/S1387700302006214 | |
| dc.identifier.uri | https://dspace.uohyd.ac.in/handle/1/11676 | |
| dc.subject | One-dimensional chain | |
| dc.subject | Polyoxometalate | |
| dc.subject | Reduction | |
| dc.subject | Tungstovanadate heteropoly complex | |
| dc.title | The first one-dimensional heteropoly tungstovanadate coordination polymer: [(V < sup > V < /sup > O < inf > 4 < /inf > )W < inf > 8 < /inf > < sup > VI < /sup > M < inf > 4 < /inf > O < inf > 36 < /inf > (V < sup > IV < /sup > O) < inf > 2 < /inf > ] < sup > n- < /sup > (M = 0.71V < sup > IV < /sup > + 0.29W < sup > VI < /sup > , n = 4.68) | |
| dc.type | Journal. Article | |
| dspace.entity.type |
Files
License bundle
1 - 1 of 1