[Ca(dipicH < inf > 2 < /inf > )(OH < inf > 2 < /inf > ) < inf > 3 < /inf > ][Ce(dipic)  < inf > 3 < /inf > ]·5H < inf > 2 < /inf > O: A One-Dimensional Coordination Polymer with Alternating CeN < inf > 3 < /inf > O < inf > 6 < /inf >  and CaNO < inf > 7 < /inf >  Polyhedra (dipicH < inf > 2 < /inf >  = Pyridine-2,6-dicarboxylic Acid)

dc.contributor.author	Swarnabala, G.
dc.contributor.author	Rajasekharan, M. V.
dc.date.accessioned	2022-03-27T09:16:57Z
dc.date.available	2022-03-27T09:16:57Z
dc.date.issued	1998-01-01
dc.description.abstract	The reaction of (NH4)2:Ce(NO3)6, and CaCl2 with dipicH2: resulted in the title compound (1). 1 crystallizes in the triclinic system, space group P1 with a = 11.234(2) Å, b = 12.719(4) Å, c = 16.142(4) Å, α = 95.63(2)°. β= 103.73(2)°, γ = 113.83(2)°, and Z=2. The structure consists of Ce(dipic)22- and Ca(dipicH2)(OH2)32+ ions linked by carboxylate groups forming an infinite linear chain having alternating tricapped trigonal prismatic and square antiprismatic polyhedra.
dc.identifier.citation	Inorganic Chemistry. v.37(7)
dc.identifier.issn	00201669
dc.identifier.uri	10.1021/ic971261l
dc.identifier.uri	https://pubs.acs.org/doi/10.1021/ic971261l
dc.identifier.uri	https://dspace.uohyd.ac.in/handle/1/12694
dc.title	[Ca(dipicH < inf > 2 < /inf > )(OH < inf > 2 < /inf > ) < inf > 3 < /inf > ][Ce(dipic) < inf > 3 < /inf > ]·5H < inf > 2 < /inf > O: A One-Dimensional Coordination Polymer with Alternating CeN < inf > 3 < /inf > O < inf > 6 < /inf > and CaNO < inf > 7 < /inf > Polyhedra (dipicH < inf > 2 < /inf > = Pyridine-2,6-dicarboxylic Acid)
dc.type	Journal. Article
dspace.entity.type

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