(5S)-1-Aza-2-imino-3-oxa-4,4-diphenylbicyclo(3.3.0)octane: a novel chiral catalytic source containing the N-(C{double bond, long}NH)-O moiety for the borane-mediated asymmetric reduction of prochiral ketones
(5S)-1-Aza-2-imino-3-oxa-4,4-diphenylbicyclo(3.3.0)octane: a novel chiral catalytic source containing the N-(C{double bond, long}NH)-O moiety for the borane-mediated asymmetric reduction of prochiral ketones
| dc.contributor.author | Basavaiah, Deevi | |
| dc.contributor.author | Venkateswara Rao, Kalapala | |
| dc.contributor.author | Sekhara Reddy, Bhavanam | |
| dc.date.accessioned | 2022-03-27T09:01:56Z | |
| dc.date.available | 2022-03-27T09:01:56Z | |
| dc.date.issued | 2007-05-16 | |
| dc.description.abstract | (5S)-1-Aza-2-imino-3-oxa-4,4-diphenylbicyclo(3.3.0)octane, a novel chiral catalytic source containing the N-(C{double bond, long}NH)-O moiety, has been synthesized and successfully utilized, for the first time, as a chiral catalytic source in the borane-mediated asymmetric reduction of prochiral ketones in refluxing toluene, to provide the corresponding secondary alcohols with up to 93% enantiomeric excess. © 2007 Elsevier Ltd. All rights reserved. | |
| dc.identifier.citation | Tetrahedron Asymmetry. v.18(8) | |
| dc.identifier.issn | 09574166 | |
| dc.identifier.uri | 10.1016/j.tetasy.2007.03.017 | |
| dc.identifier.uri | https://www.sciencedirect.com/science/article/abs/pii/S095741660700225X | |
| dc.identifier.uri | https://dspace.uohyd.ac.in/handle/1/12299 | |
| dc.title | (5S)-1-Aza-2-imino-3-oxa-4,4-diphenylbicyclo(3.3.0)octane: a novel chiral catalytic source containing the N-(C{double bond, long}NH)-O moiety for the borane-mediated asymmetric reduction of prochiral ketones | |
| dc.type | Journal. Article | |
| dspace.entity.type |
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