New economical, convenient procedures for the synthesis of catecholborane
New economical, convenient procedures for the synthesis of catecholborane
| dc.contributor.author | Kanth, Josyula V.B. | |
| dc.contributor.author | Periasamy, Mariappan | |
| dc.contributor.author | Brown, Herbert C. | |
| dc.date.accessioned | 2022-03-27T09:10:09Z | |
| dc.date.available | 2022-03-27T09:10:09Z | |
| dc.date.issued | 2000-01-01 | |
| dc.description.abstract | Catecholborane was conveniently synthesized by the reaction of tri-O-phenylene bis-borate (2) with diborane in triglyme or tetraglyme at moderate temperatures (70-80 °C). The product, catecholborane, can be distilled out in 85% yield with > 97% purity. The tri-O-phenylene bis-borate also reacts with borane-Lewis base complexes, such as BH3:DMS, BH3:THF, and BH3: NR3, with or without solvent, providing catecholborane of high purity in good yields. | |
| dc.identifier.citation | Organic Process Research and Development. v.4(6) | |
| dc.identifier.issn | 10836160 | |
| dc.identifier.uri | 10.1021/op000291w | |
| dc.identifier.uri | https://pubs.acs.org/doi/10.1021/op000291w | |
| dc.identifier.uri | https://dspace.uohyd.ac.in/handle/1/12525 | |
| dc.title | New economical, convenient procedures for the synthesis of catecholborane | |
| dc.type | Journal. Article | |
| dspace.entity.type |
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