Four-Fold Inclined Interpenetrated and Three-Fold Parallel Interpenetrated Hydrogen Bond Networks in 1,3,5-Cyclohexanetricarboxylic Acid Hydrate and Its Molecular Complex with 4,4′-Bipyridine

dc.contributor.author Bhogala, Balakrishna R.
dc.contributor.author Vishweshwar, Peddy
dc.contributor.author Nangia, Ashwini
dc.date.accessioned 2022-03-27T09:32:12Z
dc.date.available 2022-03-27T09:32:12Z
dc.date.issued 2002-09-01
dc.description.abstract Crystallization of 1,3,5-cyclohexanetricarboxylic acid (CTA) from EtOH affords the 1:1 hydrate, CTA·H2O, with 4-fold inclined interpenetrated (6,3) hydrogen-bonded networks. Crystallization of CTA with 4,4′-bipyridine (bipy) furnishes the complex, CTA·bipy·H2O (2:3:1), that has 3-fold interweaving (6,3) networks with parallel interpenetration. The striking similarity of these hydrogen bond networks to those found in the crystal structure of trimesic acid and its complex with bipy suggests that such interpenetrated networks may be engineered using retrosynthetic strategies.
dc.identifier.citation Crystal Growth and Design. v.2(5)
dc.identifier.issn 15287483
dc.identifier.uri 10.1021/cg025537y
dc.identifier.uri https://pubs.acs.org/doi/10.1021/cg025537y
dc.identifier.uri https://dspace.uohyd.ac.in/handle/1/13024
dc.title Four-Fold Inclined Interpenetrated and Three-Fold Parallel Interpenetrated Hydrogen Bond Networks in 1,3,5-Cyclohexanetricarboxylic Acid Hydrate and Its Molecular Complex with 4,4′-Bipyridine
dc.type Journal. Article
dspace.entity.type
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