CO < inf > 2 < /inf > fixation by [W IV O(S < inf > 2 < /inf > C < inf > 2 < /inf > (CN) < inf > 2 < /inf > ) < inf > 2 < /inf > ] 2- : functional model for the tungsten-formate dehydrogenase of Clostridium thermoaceticum

dc.contributor.author	Sarkar, Sabyasachi
dc.contributor.author	Das, Samar K.
dc.date.accessioned	2022-03-27T08:45:25Z
dc.date.available	2022-03-27T08:45:25Z
dc.date.issued	1992-08-01
dc.description.abstract	(NEt4)2[WIVO(S2C2(CN)2)2] (1), isolated by reaction of Na2 WO4, Na2S2C2(CN)2 (Na2mnt) in acidified (pH5.5) aqueous medium in the presence of excess of sodium dithionite and NEt4Br, reduces CO2/HCO 3 - (pH 7.5) to yield HCOO- and (NEt4)2[WVIO2(S2C2(CN)2)2] (2) mimicking tungsten-formate dehydrogenase (W-FDH) activity. (1) reacts with Na2MoO4 in acidic medium to produce [MoIvO(S2C2(CN)2)2]2- implicating the displacement of tungsten by molybdenum from the cofactor complex in W-FDH. © 1992 Indian Academy of Sciences.
dc.identifier.citation	Proceedings of the Indian Academy of Sciences - Chemical Sciences. v.104(4)
dc.identifier.issn	02534134
dc.identifier.uri	10.1007/BF02840500
dc.identifier.uri	https://link.springer.com/10.1007/BF02840500
dc.identifier.uri	https://dspace.uohyd.ac.in/handle/1/11704
dc.subject	Clostridium thermoaceticum
dc.subject	CO fixation 2
dc.subject	functional model
dc.subject	nit-1 reconstitution assay
dc.subject	tungsten-formate dehydrogenase
dc.title	CO < inf > 2 < /inf > fixation by [W < sup > IV < /sup > O(S < inf > 2 < /inf > C < inf > 2 < /inf > (CN) < inf > 2 < /inf > ) < inf > 2 < /inf > ] < sup > 2- < /sup > : functional model for the tungsten-formate dehydrogenase of Clostridium thermoaceticum
dc.type	Journal. Article
dspace.entity.type

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CO < inf > 2 < /inf > fixation by [W < sup > IV < /sup > O(S < inf > 2 < /inf > C < inf > 2 < /inf > (CN) < inf > 2 < /inf > ) < inf > 2 < /inf > ] < sup > 2- < /sup > : functional model for the tungsten-formate dehydrogenase of Clostridium thermoaceticum