Reverse-Keggin ions: Polycondensation of antimonate ligands give inorganic cryptand
Reverse-Keggin ions: Polycondensation of antimonate ligands give inorganic cryptand
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Date
2007-03-21
Authors
Baskar, Viswanathan
Shanmugam, Maheswaran
Helliwell, Madeleine
Teat, Simon J.
Winpenny, Richard E.P.
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Abstract
Reverse-Keggin ions are reported in which a p-block element (antimony) occupies the twelve vertices of a truncated tetrahedron while a d-block element (manganese or zinc) occupies the tetrahedral central cavity. The exterior of the reverse-Keggins also acts as tridentate ligands to further d-block centers. Copyright © 2007 American Chemical Society.
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Journal of the American Chemical Society. v.129(11)