Baylis–Hillman Reaction: In Situ Generated Isoquinolinium Species as Excellent Electrophiles for Coupling with Alkyl Acrylates and Acrylonitrile

dc.contributor.author	Basavaiah, Deevi
dc.contributor.author	Thamizharasi, Perumal
dc.date.accessioned	2022-03-27T09:00:45Z
dc.date.available	2022-03-27T09:00:45Z
dc.date.issued	2017-09-15
dc.description.abstract	Isoquinolinium species, generated in situ from 2-alkynylbenzaldehydes, arylamines, and silver trifluoromethanesulfonate, were successfully employed as excellent electrophiles for Baylis–Hillman coupling with alkyl acrylates (or acrylonitrile) under the influence of 1,4-diazabicyclo[2.2.2]octane to provide 1,2,3-trisubstituted dihydroisoquinoline derivatives in high yields.
dc.identifier.citation	European Journal of Organic Chemistry. v.2017(34)
dc.identifier.issn	1434193X
dc.identifier.uri	10.1002/ejoc.201700743
dc.identifier.uri	https://onlinelibrary.wiley.com/doi/10.1002/ejoc.201700743
dc.identifier.uri	https://dspace.uohyd.ac.in/handle/1/12263
dc.subject	Baylis–Hillman reaction
dc.subject	Electrophiles
dc.subject	Fused-ring systems
dc.subject	Nitrogen heterocycles
dc.subject	Reactive intermediates
dc.title	Baylis–Hillman Reaction: In Situ Generated Isoquinolinium Species as Excellent Electrophiles for Coupling with Alkyl Acrylates and Acrylonitrile
dc.type	Journal. Article
dspace.entity.type

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