Statistics for Structural Effects in Solvolytic Reactions. 38. Carbon-13 Nuclear Magnetic Resonance Studies of Carbocations. 6. < sup > 1 < /sup > Effect of Increasing Electron Demand on the Chemical Shifts of the α-Carbon Atoms in Substituted Aryldialkyl Carbocations. Correlation of the Data with a New Set of Substituent Constants, σ < sup > αC+ < /sup >
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