Rhenium-based bicyclic supramolecule with calixarene-shaped bowls
Rhenium-based bicyclic supramolecule with calixarene-shaped bowls
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Date
2013-02-01
Authors
Rajakannu, Palanisamy
Elumalai, Palani
Hussain, Firasat
Sathiyendiran, Malaichamy
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Abstract
The reaction of Re2(CO)10 with chloranilic acid (H2-CA) and 1,3,5-tris(2-methylmercaptobenzimidazol-1-ylmethyl)-2,4, 6-trimethylbenzene (L) gives a heteroleptic cycle [(fac-Re(CO)3) 6(CA)3(L)2] (1). The hexanuclear metallacycle 1 possesses calixarene-shaped bowls. © 2012 Elsevier B.V. All rights reserved.
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Keywords
Calixarene,
Flexible donor,
Metallacycle,
Rhenium,
Supramolecule
Citation
Journal of Organometallic Chemistry. v.725