Silver-Catalyzed Synthesis of Enones/α-Iodoenones from Tertiary Propargyl Alcohols
Silver-Catalyzed Synthesis of Enones/α-Iodoenones from Tertiary Propargyl Alcohols
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Date
2019-12-13
Authors
Naveen, Naganaboina
Ramesh, Golla
Balamurugan, Rengarajan
Journal Title
Journal ISSN
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Abstract
Tertiary propargyl alcohols undergo smooth Meyer-Schuster rearrangement to give enones in the presence of silver catalyst alone at room temperature. The intermediate can be trapped using NIS to make useful tetra substituted α-iodoenones.
Description
Keywords
AgSbF 6,
Meyer-Schuster rearrangement,
Tertiary propargyl alcohols,
α -iodoenones,
α,β-unsaturated enones
Citation
ChemistrySelect. v.4(46)