Paramagnetic keplerate "necklaces" synthesized by a novel room-temperature solid-state reaction: Controlled linking of metal-oxide-based nanoparticles
Paramagnetic keplerate "necklaces" synthesized by a novel room-temperature solid-state reaction: Controlled linking of metal-oxide-based nanoparticles
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Date
2002-02-15
Authors
Müller, Achim
Das, Samar K.
Talismanova, Marina O.
Bögge, Hartmut
Kögerler, Paul
Schmidtmann, Marc
Talismanov, Sergei S.
Luban, Marshall
Krickemeyer, Erich
Journal Title
Journal ISSN
Volume Title
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Abstract
Crsytal engineering with nanoobjects? Spherical structurally well-defined molybdenum-oxide-based giant clusters can be appropriately functionalized to a crystalline material with the remarkable property of having discrete cluster units which get covalently linked to form chains (see pictures) through Fe-O-Mo bonds after having approached each other as a result of the release of crystal water upon drying.
Description
Keywords
Composites,
Magnetic properties,
Molybdenum,
Polyoxometalates,
Supramolecular chemistry
Citation
Angewandte Chemie - International Edition. v.41(4)