Amorphous-to-crystalline transformation with fluorescence enhancement and switching of molecular nanoparticles fixed in a polymer thin film

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Date
2012-11-19
Authors
Chandaluri, Ch G.
Radhakrishnan, T. P.
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Abstract
Growth in a confined environment: A protocol for the amorphous-to- crystalline transformation (ACT) of nanoparticles has been developed, the critical step being the partial confinement of the particles by fixing in a polymer thin film and solvent vapor fuming. The ACT of a diaminodicyanoquinodimethane-based nanoparticle is accompanied by substantial fluorescence enhancement and switching of the emission color. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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Keywords
amorphous materials, fluorescence, nanoparticles, polymers, thin films
Citation
Angewandte Chemie - International Edition. v.51(47)