The Baylis-Hillman acetates as a source of ambiphilic molecules: A simple synthesis of 1,3-thiazinane-2-thione frameworks

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Date
2015-06-04
Authors
Basavaiah, Deevi
Pal, Sutanuka
Veeraraghavaiah, Gorre
Bharadwaj, Kishor Chandra
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Journal ISSN
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Abstract
Ambiphilic molecules (allylamines 1), easily accessible from the Baylis-Hillman acetates, have been effectively utilized for stereoselective synthesis of cis-5,6-disubstituted-1,3-thiazinane-2-thione derivatives (2) via the reaction with carbon disulfide as a bridging partner.
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Keywords
1,3-Thiazinane-2-thiones, Ambiphilic molecules, Baylis-Hillman acetates, Bridging partner, Carbon disulfide
Citation
Tetrahedron. v.71(28)