A novel, tandem construction of C-N and C-C bonds: Facile and one-pot transformation of the Baylis-Hillman adducts into 2-benzazepines
A novel, tandem construction of C-N and C-C bonds: Facile and one-pot transformation of the Baylis-Hillman adducts into 2-benzazepines
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Date
2004-01-01
Authors
Basavaiah, Deevi
Satyanarayana, Tummanapalli
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Abstract
A novel reaction involving tandem construction of C-N and C-C bonds via the simultaneous Ritter and Houben-Hoesch reactions on Baylis-Hillman adducts leading to a convenient, one-pot synthesis of 2-benzazepine derivatives is described. A facile stereoselective transformation of the Baylis-Hillman adducts into (E)- and (Z)-allyl amides is also presented. © 2004 Royal Society of Chemistry.
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Chemical Communications. v.4(1)