First enantioselective synthesis of mikanecic acid via Diels-Alder cycloaddition mediated construction of chiral vinylic quaternary center
First enantioselective synthesis of mikanecic acid via Diels-Alder cycloaddition mediated construction of chiral vinylic quaternary center
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Date
1994-06-13
Authors
Basavaiah, Deevi
Pandiaraju, Subramanian
Sarma, Pakala K.S.
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Abstract
Chiral mikanecic acid (1) was synthesized in 74% enantiomeric purity (92% ee after crystallization) via asymmetric Diels-Alder reaction of a novel in situ generated chiral 1,3-butadiene-2-carboxylate (A). © 1994.
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Tetrahedron Letters. v.35(24)