The synthesis of novel chiral macrocyclic and polymeric amines containing a trans-1,2-diaminocyclohexane system
The synthesis of novel chiral macrocyclic and polymeric amines containing a trans-1,2-diaminocyclohexane system
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Date
2004-08-09
Authors
Padmaja, Meduri
Periasamy, Mariappan
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Abstract
The reactions of (R,R)-N,N′-diisopropyl-1,2-diaminocyclohexane with isomeric benzylic dibromides gave heterocycles and macrocycles. Additionally a reaction with adipoyl chloride gave a polymeric amido carboxylic acid that could be readily reduced to the corresponding polyamino alcohol using the NaBH 4/I 2 reagent system. © 2004 Published by Elsevier Ltd.
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Tetrahedron Asymmetry. v.15(15)