A novel arylation of arylacetic acid esters using tertiary arylamines and TiCl < inf > 4 < /inf >
A novel arylation of arylacetic acid esters using tertiary arylamines and TiCl < inf > 4 < /inf >
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Date
2003-12-08
Authors
Periasamy, Mariappan
KishoreBabu, N.
Jayakumar, Keela Natarajan
Journal Title
Journal ISSN
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Abstract
The reactions of arylacetic acid esters with tertiary arylamines in the presence of TiCl4 give α-arylated products in 65-90% yields, as well as 10-20% yields of the corresponding benzidines. © 2003 Elsevier Ltd. All rights reserved.
Description
Keywords
Aryltitanium,
Cross coupling reactions,
Diaryl acetic esters,
Titanium enolates
Citation
Tetrahedron Letters. v.44(50)