Catalytic effect of a BH < inf > 3 < /inf > : N,N-diethylaniline complex in the formation of alkenyl catecholboranes from alk-1-ynes and catecholborane
Catalytic effect of a BH < inf > 3 < /inf > : N,N-diethylaniline complex in the formation of alkenyl catecholboranes from alk-1-ynes and catecholborane
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Date
1990-12-01
Authors
Suseela, Yantrapragada
Prasad, A. S.Bhanu
Periasamy, Mariappan
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Abstract
Alkenyl catecholboranes are readily formed by the reaction of catecholborane and alk-1-ynes at 25°C, in the presence of 10 mol% of a BH3:N,N-diethylaniline complex, via a hydroboration-alkenyl transfer mechanism.
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Journal of the Chemical Society, Chemical Communications