Reaction of allenylphosphonates/allenylphosphine oxides with thiocyanates/isothiocyanates or oxalyl chloride/AgNO < inf > 3 < /inf >
Reaction of allenylphosphonates/allenylphosphine oxides with thiocyanates/isothiocyanates or oxalyl chloride/AgNO < inf > 3 < /inf >
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Date
2017-06-03
Authors
Swamy, K. C.Kumara
Chakravarty, Manab
Debnath, Shubham
Reddy, M. Nagarjuna
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Abstract
In this paper, we describe thiocyanation as well as chlorination of selected allenylphosphonates/allenyl phosphine oxide, using ammonium thiocaynate or (OCH2CMe2CH2O)PNCS (for thiocyanation) or oxalyl chloride/AgNO3 for chlorination. The resulting products are vinyl (thiocyanato)phosphonates or vicinal dichloro(vinyl) phosphonates. One of the vinyl thiocyanato-phosphonates is characterized by single crystal X-ray crystallography.
Description
Keywords
Allenes,
allenylphosphine oxides,
allenylphosphonates,
vicinal dichloro vinylphosphonates,
vinyl thiocyanato-phosphonate
Citation
Phosphorus, Sulfur and Silicon and the Related Elements. v.192(6)