The 1:1 antimony trichloride adduct of chlorobis(2,6-dimethylpiperidin-1-yl)-phosphine oxide
The 1:1 antimony trichloride adduct of chlorobis(2,6-dimethylpiperidin-1-yl)-phosphine oxide
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Date
1997-12-15
Authors
Vijjulatha, M.
Swamy, K. C.Kumara
Huch, Volker
Veith, Michael
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Abstract
In the structure of the title complex, [(C7H14N)2Cl-P(O)].SbCl3, the Sb atom shows a distorted trigonal bipyramidal geometry (including the lone pair). The O-Sb interaction of antimony with the phosphoryl O atom is only moderate and is weaker than that observed in the known compound Cl3PO→SbCl5.
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Acta Crystallographica Section C: Crystal Structure Communications. v.53(12)