A study toward understanding the role of a phosphorus stereogenic center in (5S)-1,3-diaza-2-phospha-2-oxo-3-phenylbicyclo(3.3.0)octane derivatives as catalysts in the borane-mediated asymmetric reduction of prochiral ketones
A study toward understanding the role of a phosphorus stereogenic center in (5S)-1,3-diaza-2-phospha-2-oxo-3-phenylbicyclo(3.3.0)octane derivatives as catalysts in the borane-mediated asymmetric reduction of prochiral ketones
| dc.contributor.author | Basavaiah, Deevi | |
| dc.contributor.author | Chandrashekar, Vanampally | |
| dc.contributor.author | Das, Utpal | |
| dc.contributor.author | Reddy, Gone Jayapal | |
| dc.date.accessioned | 2022-03-27T09:02:17Z | |
| dc.date.available | 2022-03-27T09:02:17Z | |
| dc.date.issued | 2005-12-12 | |
| dc.description.abstract | Representative diastereomeric pairs of chiral catalysts, containing the (5S)-1,3-diaza-2-phospha-2-oxo-3-phenylbicyclo(3.3.0)octane moiety, with different stereochemistry at the phosphorus stereogenic center, have been synthesized and their stereoselection in the borane-mediated asymmetric reduction of representative prochiral ketones has been described. © 2005 Elsevier Ltd. All rights reserved. | |
| dc.identifier.citation | Tetrahedron Asymmetry. v.16(24) | |
| dc.identifier.issn | 09574166 | |
| dc.identifier.uri | 10.1016/j.tetasy.2005.10.038 | |
| dc.identifier.uri | https://www.sciencedirect.com/science/article/abs/pii/S0957416605008414 | |
| dc.identifier.uri | https://dspace.uohyd.ac.in/handle/1/12309 | |
| dc.title | A study toward understanding the role of a phosphorus stereogenic center in (5S)-1,3-diaza-2-phospha-2-oxo-3-phenylbicyclo(3.3.0)octane derivatives as catalysts in the borane-mediated asymmetric reduction of prochiral ketones | |
| dc.type | Journal. Article | |
| dspace.entity.type |
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