EPR STUDIES OF MIXED VALENCE INTERACTIONS IN Mn(III,IV) COMPLEXES.
EPR STUDIES OF MIXED VALENCE INTERACTIONS IN Mn(III,IV) COMPLEXES.
No Thumbnail Available
Date
1984-12-01
Authors
Swarnabala, G.
Umashankar, M.
Rajasekharan, M. V.
Journal Title
Journal ISSN
Volume Title
Publisher
Abstract
EPR studies of oxo-bridged dimeric Mn(III,IV) complexes of bpy, 4,4 prime -(Me)//2bpy, 5,5 prime -(Me)//2bpy, and 6,6 prime -(Me)//2bpy show that the electron transfer rate is sensitive to methylation at the 6-position. We report the EPR results for Mn(III,IV) complexes with symmetrically methylated bpy ligands.