Self-assembly of rhenium core-based conjoined bicyclic supramolecule from pyrazole and flexible hexatopic pyrazolyl ligands

dc.contributor.author	Phukon, Upasana
dc.contributor.author	Priyatharsini, Maruthupandiyan
dc.contributor.author	Sathiyendiran, Malaichamy
dc.date.accessioned	2022-03-27T08:35:37Z
dc.date.available	2022-03-27T08:35:37Z
dc.date.issued	2020-09-15
dc.description.abstract	Self-assembly of rhenium core-based conjoined bicyclic supramolecule from pyrazole and flexible hexatopic pyrazolyl ligands is demonstrated in a study. The study reports unexpected conjoined bicyclic supramolecular coordination complex (SCC) with free two pyrazolyl motifs via a new type of metal-ligand bonding combinations from Re2(CO) 10, pyrazole, water, and flexible hexatopic pyrazolyl N-donors in a one-pot solvothermal process. The crystals are air and moisture-stable and soluble in DMSO. The FT-IR spectrum of the complex displayed three strong bands, which are the characteristic peaks for the fac-Re(CO) 3 core in the complex.
dc.identifier.citation	Journal of Organometallic Chemistry. v.923
dc.identifier.issn	0022328X
dc.identifier.uri	10.1016/j.jorganchem.2020.121460
dc.identifier.uri	https://www.sciencedirect.com/science/article/abs/pii/S0022328X20303624
dc.identifier.uri	https://dspace.uohyd.ac.in/handle/1/11090
dc.title	Self-assembly of rhenium core-based conjoined bicyclic supramolecule from pyrazole and flexible hexatopic pyrazolyl ligands
dc.type	Journal. Article
dspace.entity.type

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