Prototype rhenium metallocavitand with four exocyclic cavities for small molecules

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Date
2022-02-01
Authors
Kedia, Moon
Priyatharsini, Maruthupandiyan
Sathiyashivan, Shankar Deval
Shankar, Bhaskaran
Krishnakumar, Rajaputi Venkatraman
Sathiyendiran, Malaichamy
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Abstract
Neutral trinuclear metallocavitand possessing three-types of molecular receptor units (A, B, and C; four exocyclic calixarene-shaped cavities (A and C) and one endocyclic cavity (B)) suitable to accommodate small ion/neutral molecules were obtained from Re2(CO)10, benzimidazole, and 1,3,5-tris(benzimidazol-1-ylmethyl)benzene in a one-pot approach.
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Keywords
Benzimidazole, Cage, Calixarene, Cavitand, Rhenium, Supramolecules
Citation
Journal of Organometallic Chemistry. v.959