Probing the <sup>2</sup>B<inf>2</inf>-<sup>2</sup>A<inf>1</inf> conically intersecting electronic states of ClO<inf>2</inf> through photodetachment spectroscopy of its negative ion
Probing the <sup>2</sup>B<inf>2</inf>-<sup>2</sup>A<inf>1</inf> conically intersecting electronic states of ClO<inf>2</inf> through photodetachment spectroscopy of its negative ion
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Date
2003-05-15
Authors
Krishnan, Gireesh M.
Mahapatra, Susanta
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Abstract
A detailed theoretical account of the photodetachment dynamics of ClO2- was carried out. For this purpose, the near-equilibrium ab initio C2v PESs of Peterson and Werner was extended to Cs configurations assuming a harmonic vibration along the asymmetric stretch coordinate. The nuclear dynamics was studied with the aid of a time-dependent WP method.
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Journal of Chemical Physics. v.118(19)